Characterizing Iron Based Historical Specimens - Buehler

Roman Nail, Broken below Head, Found in Vicenza, Italy - Montage of the broken Roman nail (left, Klemm’s I) and view of a typical large slag stringer (2% nital).

Patches of as-quenched martensite were found in the carburized nail head. Picral will not etch as-quenched martensite, but it will etch tempered martensite.
Patches of as-quenched martensite within the pearlitic carburized head revealed using 10% sodium metabisulfite.
Most of the head, but not in the center of the top face, was carburized. Etched with Beraha’s sulfamic acid 3/1 reagent (left) and Klemm’s I (right) and imaged with polarized light and sensitive tint.
Montage of the microstructure starting from under the head at the left corner (C –carburized) and going inward at the top of the shaft (AF –acicular ferrite; S –slag; EF –equiaxed ferrite). Klemm’s I, polarized light and sensitive tint used to image the structure.
Microstructure in the shaft (left, center and right side, respectively) revealing numerous mechanical twins (Neumann Bands) and slag stringers in a ferritic matrix. Beraha’s sulfamic acid (3/1) solution used with polarized light and sensitive tint to image the microstructure.
Higher magnification view of the mechanical twins in the ferrite in the shaft above the break (Beraha’s 3/1 sulfamic acid reagent, XP+ST).

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resourcesThe articles and presentations that can be down-loaded from this web site are based upon work done by GFV while employed at Bethlehem Steel (1967-1983), Carpenter Technology (1983-1996), Buehler Ltd. (1996-2009) and Struers (2009-Present) and from the authors consulting work for companies such as, Latrobe Steel, Scot Forge, etc., and from his litigation work. GFV's bylined articles appearing in various issues of the ASM Handbook series have been listed here courtesy of ASM International, Materials Park, Ohio.

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